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Colored gases - chlorine and chlorine dioxide
. Two experiments
are performed. In one of them, chlorine gas is made from dilute
hydrochloric acid and calcium hypochlorite. In the other, chlorine
dioxide is made from sodium chlorate and concentrated hydrochloric acid.
The chlorine dioxide has a really intense yellow color. |
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Volatile compounds of chromium -
another colored gas
. In this
experiment, two volatile compounds of chromium are made from potassium
dichromate, sodium fluoride, sodium chloride and concentrated sulphuric
acid. One of them produces an orange/brown vapor, which very much
resembles bromine vapor. |
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More fun with volatile chromium - chromyl
chloride
. This is a really
beautiful experiment. Chromyl chloride vapor is poured on a very dilute
acidified solution of hydrogen peroxide. On the surface, the chromyl
chloride vapor is absorbed by the liquid and heavy streams of a peroxo
complex of chromium are formed, which produce nice deep blue patterns in
the liquid. |
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Violent 'combustion' of acetylene in
chlorine gas
. Acetylene gas,
made from reacting water with calcium carbide (a.k.a. 'carbid) is
bubbled into an erlenmeyer, filled with chlorine gas. This results in
violent explosions inside the erlenmeyer. Spectacular, but also somewhat
scary. |
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Decomposition of iodoform, purple iodine vapor.
A small amount of iodoform is heated in a test tube, and it is shown how
this decomposes, giving purple vapor of iodine. |
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Reaction between molten nitrite
and iodate, beautiful red gas mix. Some potassium hydrogen diiodate
(double salt of potassium iodate and iodic acid) is mixed with sodium
nitrite and the mix is heated. This gives a mix of nitrogen dioxide and
iodine vapor. This mix has a beautiful color. |
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Volatile compound of
niobium - rime and snow. This is an experiment at the border of
chemistry and physics. Some niobium pentachloride is heated, until all
of it has become a vapor. The vapor has a deep yellow color. On cooling
down, the vapor condenses to a very fine snow-like material. Inside the
test tube, one can see the 'snow' falling. Also, rime is formed. This is
a beautiful somewhat mysterious experiment. |
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Volatile compound of tin with yellow vapor
color. Tin and iodine are made to react in a suitable solvent for
iodine. Under these conditions the interesting compound tin(IV) iodide
is formed, which can easily be isolated. This compound is volatile and
only moderate heating is needed to give a dense yellow/brown vapor. |
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Volatile vanadium compound, leading to
green gas and red smoke.
Phosphorus pentachloride is capable of chlorinating vanadium pentoxide
and the resulting compound is volatile and gives rise to formation of
interesting yellow/green vapor and red smoke when it is heated. |
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Reaction in gas phase. Nitrogen monoxide
and oxygen are prepared and mixed by setting up an apparatus with two
glass bottles. As soon as the gases mix, a deep brown gas is formed.
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Electrolysis of water --
detonating gas. Water is decomposed by means of electrolysis of a
dilute sulphuric acid solution. The resulting gases are mixed and the
impressive explosive power of this gas mix is demonstrated. |
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Precision electrolysis of acetate and
formiate. Acetate and formiate are electrolysed and based on the
observations in this experiment, the net reactions are derived. A
demonstration of what can be achieved with a combination of careful
observation and reasoning. |
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Color of the flame of burning gases.
Different gases are collected in a test tube, sucked in a syringe, and
then ignited. Many different flame colors can be obtained from different
gases. Some flame colors are remarkable, such as pink/rose and grey. |
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Explosive properties of chlorine
dioxide
. The brightly
colored chlorine dioxide gas is prepared and ignited. This results in a
nice and quite spectacular decompositon reaction. |
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Explosion of chlorine dioxide, initiated
by presence of ammonia
. Another
experiment, which demonstrates the danger of chlorine dioxide. This
experiment shows how chlorine dioxide can be brought to explosion,
simply by adding a few drops of household ammonia. |
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Barking dog reaction
. Nitrous oxide is
mixed with carbon disulfide vapor and this mix is ignited. This results
in a very spectacular reaction with bright light and an impressive
barking noise. |
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Self-ignition of
phosphine in chlorine gas
.
In this experiment some phosphine is prepared, and the gas is bubbled in
an atmosphere of chlorine, resulting in self-ignition of the gas and
contraction of gas volume. |
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Formation of a self-igniting gas from fine
sand powder and magnesium
. Magnesium metal
and finely powdered sand are reacted to form magnesium silicide, which
in contact with dilute acids produces self-igniting silane gas. This is
a spectacular, but somewhat dangerous experiment. |
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Concentrating and purification of
ammonia.
Ordinary household ammonia is concentrated and purified by heating the
liquid, driving out the gas and leading that gas through distilled
water. This process can be used to make very pure ammonia at a higher
concentration than the plain household ammonia. |