|
element |
required compound |
link to experiment |
* |
O |
H2O2
(30%)
swimming
pool tablets |
Red chemiluminiscence with chlorine
swimming pool chemicals. Hydrogen peroxide is added to sodium
dichloro isocyanurate or to calcium hypochlorite. A nice red
chemiliminiscent light is produced. |
|
O,
Cr |
K2Cr2O7
H2O2
any mineral acid |
Beautiful effects with potassium
dichromate and hydrogen peroxide. Potassium dichromate crystals are
sprinkled on a highly diluted acidic hydrogen peroxide solution. The
effect is stunning. |
|
O,
Cr |
K3CrO8 |
Explosive properties
of peroxo chromates. A synthesis method for this chemical is given, and
its explosive properties are shown. |
* |
O, Cr |
K2Cr2O7
NaF
NaCl
H2SO4
(concentrated)
H2O2 |
Fun with volatile chromium - chromyl
chloride
. A really
beautiful experiment with chromyl chloride vapor, which is poured on a
very dilute acidic hydrogen peroxide solution. |
* |
O, Ni,
Ag |
Na2S2O8
HNO3
(dilute)
AgNO3
NiSO4·xH2O
NaOH |
Very high oxidation state of nickel
and silver with persulfate. Nickel is brought to +3 or even +4 oxidation state
by persulfate ion under alkaline conditions. |
* |
O |
H2O2
many metal
salts
HCl (10%)
NH3 (5%) |
Peroxo complexes of transition metals in
high oxidation states. Many transition metals show colorful and
sometimes remarkable peroxo complexes when they are in high oxidation
states. |
* |
O, Cr |
H2O2
(NH4)2CrO4
NH3
(25%) |
Synthesis of triammine diperoxo
chromium(IV).
This is a
description of how to make a very energetic chromium peroxo compound.
Also some properties of the prepared compound are shown. |
* |
O, Cr |
H2O2
Na2Cr2O7·2H2O
C5H5N
(pyridine)
Na2SO3
H2SO4
|
Chromium peroxo pyridine complex
and its properties.
A dark blue insoluble peroxo complex of chromium is made, and some
further experiments are performed with this compound. This experiments
shows some remarkable color combinations and the peroxo complex is
remarkably stable under reducing conditions. |
* |
O, V |
V2O5
KOH
H2O2
(15%)
H2SO4
(dilute)
CH3CH2OH
(96%)
P (red) |
Isolation of peroxo complex of vanadium.
In this experiment a peroxo complex of vanadium is made and this complex
is isolated as a dry powdered solid. The isolated compound is stable on
storage and has energetic properties. A mix with red phosphorus
deflagrates on ignition. |
* |
O, Cr |
H2O2
K2Cr2O7
KOH |
Synthesis of potassium tetraperoxo
chromate(V)
. A detailed description (recipe) for making the
energetic compound K3CrO8. |