Experiments with peroxides and other oxygen compounds

 

  element required compound link to experiment
*

O

H2O2 (30%)

swimming pool tablets

Red chemiluminiscence with chlorine swimming pool chemicals. Hydrogen peroxide is added to sodium dichloro isocyanurate or to calcium hypochlorite. A nice red chemiliminiscent light is produced.

 

O, Cr

K2Cr2O7

H2O2

any mineral acid

Beautiful effects with potassium dichromate and hydrogen peroxide. Potassium dichromate crystals are sprinkled on a highly diluted acidic hydrogen peroxide solution. The effect is stunning.

 

O, Cr

K3CrO8

Explosive properties of peroxo chromates. A synthesis method for this chemical is given, and its explosive properties are shown.

*

O, Cr

K2Cr2O7

NaF

NaCl

H2SO4 (concentrated)

H2O2

Fun with volatile chromium - chromyl chloride . A really beautiful experiment with chromyl chloride vapor, which is poured on a very dilute acidic hydrogen peroxide solution.

*

O, Ni, Ag

Na2S2O8

HNO3 (dilute)

AgNO3

NiSO4·xH2O

NaOH

Very high oxidation state of nickel and silver with persulfate. Nickel is brought to +3 or even +4 oxidation state by persulfate ion under alkaline conditions.

*

O

H2O2

many metal salts

HCl (10%)

NH3 (5%)

Peroxo complexes of transition metals in high oxidation states. Many transition metals show colorful and sometimes remarkable peroxo complexes when they are in high oxidation states.

*

O, Cr

H2O2

(NH4)2CrO4

NH3 (25%)

Synthesis of triammine diperoxo chromium(IV). This is a description of how to make a very energetic chromium peroxo compound. Also some properties of the prepared compound are shown.

* O, Cr

H2O2

Na2Cr2O7·2H2O

C5H5N (pyridine)

Na2SO3

H2SO4

Chromium peroxo pyridine complex and its properties. A dark blue insoluble peroxo complex of chromium is made, and some further experiments are performed with this compound. This experiments shows some remarkable color combinations and the peroxo complex is remarkably stable under reducing conditions.
* O, V

V2O5

KOH

H2O2 (15%)

H2SO4 (dilute)

CH3CH2OH (96%)

P (red)

Isolation of peroxo complex of vanadium. In this experiment a peroxo complex of vanadium is made and this complex is isolated as a dry powdered solid. The isolated compound is stable on storage and has energetic properties. A mix with red phosphorus deflagrates on ignition.
*

O, Cr

H2O2

K2Cr2O7

KOH

Synthesis of potassium tetraperoxo chromate(V) . A detailed description (recipe) for making the energetic compound K3CrO8.

 

 

   

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