Experiments with antimony, bismuth or their compounds

 

  element required compound link to experiment
*

Bi

Bi(NO3)3·xH2O

HNO3 (dilute)

HCl (dilute)

NaCl

KBr

KI

Bismuth complexes with halogens. Bismuth in its +3 oxidation state forms a black precipitate with iodide ions, and a deep orange complex is formed when excess iodide ion is present. Chloride and bromide also form complexes.

 

Sb

Sb2S3

HCl (30%)

Antimony sesquisulfide, stunning change of its appearance when it is hydrated. Some pyro-grade black antimony sesquisulfide is dissolved in conc. hydrochloric acid. When the solution is diluted, then hydrolysis occurs and a bright yellow precipitate of hydrated antimony sesquisulfide is produced.

 

 

   

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