Description of experiment
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experiment.
Needed compounds: ----------------- sulphuric acid : H2SO4 sodium persulfate : Na2S2O8 p-aminophenol HCl : NH2 C6H4 OH . HCl metol : (CH3 NH C6H4 OH)2 . H2SO4
Class: ------ elem=C redox
Summary: -------- Both metol and p-aminophenol HCl are oxidized by persulfate to colored compounds. When metol is used, the color, however, is not as brilliant and not as intense as when p-aminophenol HCl is used. Apparently the methyl-group on the amino-part of metol has strong influence on the color of the oxidation product or on the type of oxidation products.
Description: ------------ Add some p-aminophenol HCl and some sodium persulfate to dilute sulfuric acid (appr. 7% by weight) and heat to appr. 60 C: An intense indigo/purple compound is formed, the liquid becomes indigo/purple and remains clear.
Add some metol (n-methyl p-aminophenol sulfate) and some sodium persulfate to dilute sulfuric acid (appr. 7% by weight) and heat to appr. 60 C: The liquid turns pink/brown. The intensity of the color is much less than when p-aminophenol is used.
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