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Experiments for 'vanadium pentoxide'
Below follows a summary of all experiments, matching your
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experiment.
Results for 'vanadium pentoxide':
EXPERIMENT 1 --------------- Vanadium pentoxide hardly dissolves in water. In acid it dissolves slightly better, but even then its solubility is small.
EXPERIMENT 2 --------------- Vanadium pentoxide can be easily dissolved in acid, when a reductor is present. Then it is dissolved and at the same time reduced to vanadyl (vanadium (V) to vanadium (IV)). With very strong reducing compounds, further reduction to vanadium (III) or even vanadium (II) is possible.
EXPERIMENT 3 --------------- Vanadium (V) builds different kinds of poly-vanadates, with colors ranging from colorless to deep orange/red.
EXPERIMENT 4 --------------- Hydrogen peroxide builds complexes with vanadium (IV) and vanadium (V) species. These compounds are not stable and result in dissociation of the complex and formation of vanadium (IV) compounds. The net result of adding hydrogen peroxide to a solution containing vanadium (V) can be reduction to vanadium (IV) with the formation of oxygen.
EXPERIMENT 5 --------------- Vanadium (IV) does not build complexes with EDTA in acidic environments.
EXPERIMENT 6 --------------- Vanadium (V) compounds can coexist with ferricyanide in solution. Reduction of either one of them results in formation of a precipitate.
EXPERIMENT 7 --------------- Hydroxyl amine is capable of reducing vanadium (V) to vanadium (IV), but further reduction is not possible with hydroxyl amine.
EXPERIMENT 8 --------------- Sulfide reacts with metavanadates, resulting in the formation of a dark brown/greenish compound.
EXPERIMENT 9 --------------- Vanadium (IV) does not readily yield precipitates with alkaline compounds. Carbonate is not capable of precipitating this. Hydrogen peroxide builds a complex with vanadium (V) and possibly with vanadium (IV). Diverse coloured compounds are formed in sequence. What is their constitution?
EXPERIMENT 10 --------------- The result of this experiment is remarkable. Hydroxyl amine, being a strong reductor, appears to oxidize vanadium (IV) to vanadium (V) in alkaline environments. Or is there another compound, which strongly resembles the well-known yellow colour of vanadium (V) in acidic environments and the (almost) colourless appearance of vanadium (V) in alkaline environments?
EXPERIMENT 11 --------------- Vanadium pentoxide dissolves in ammonia and when heated a white solid is formed, probably this is ammonium meta vanadate.
EXPERIMENT 12 --------------- Vanadium pentoxide reacts with ammonia, producing a strong hissing noise. A white compound is created. This probably is ammonium metavanadate, NH4VO3.
EXPERIMENT 13 --------------- Vanadium (V) compounds form yellow compouds with hydrogen peroxide in alkaline environments, with strong solutions and very high alkalinity grey and blue compounds are formed, which, however, decompose easily.
EXPERIMENT 14 --------------- Vanadium pentoxide can be dissolved in very concentrated solutions of NaOH in considerable quantities. When such a solution is cooled down, then a white crystalline solid separates from the liquid and the liquid completely solidifies.
EXPERIMENT 15 --------------- Vanadium (V) is capable of forming many peroxo compounds, whose appearance strongly depends on pH.
EXPERIMENT 16 --------------- Without the help of a strong acid, vanadium pentoxide is not capable of oxidizing formic acid, not even when heated. When some sulfite is added, then incomplete reduction of the V2O5 can be observed. With the help of a strong acid and when in solution, vanadium (V) is capable of oxidizing formic acid, but only very slowly. With formic acid and vanadium (IV), apparently a coordination complex is formed. Another explanation is given below at the end of the description.
EXPERIMENT 17 --------------- Vanadium in its +4 oxidation state forms a blue compound, vanadyl, in acidic environments. In near neutral to alkaline environments, the situation is less clear. Reduction of neutral or alkaline vanadium (V) compounds yields a dark and turbid liquid. Vanadium in its +5 oxidation state gives light yellow compounds in mildly alkaline environments. Al lowering the pH, the color becomes more intense, until a maximum is reached. When the pH is lowered even more, then lighter yellow compounds are formed again. Vanadium (IV) cannot coexist with hydrogen peroxide. In alkaline media it is oxidized to vanadium (V), which with excess peroxide gives a yellow peroxo complex. In acidic media, vanadium (IV) is oxidized to vanadium (V) which gives a deep brown/red peroxo complex with excess poroxide.
EXPERIMENT 18 --------------- Vanadium pentoxide dissolves in concentrated sulphuric acid with some heating. A deep red liquid is formed, which, remarkably, only is reduced by sulfite in the presence of some water.
EXPERIMENT 19 --------------- Chromium (III) cannot be oxidized to chromium (VI) by vanadium (V) species or bromates in strongly alkaline environments. Peroxodisulfate is capable of achieving this.
EXPERIMENT 20 --------------- Hydroquinone is oxidized by chlorate, but this reactions proceeds slowly. When vanadium pentoxide is added in small quantities, then the reaction proceeds much faster. The vanadium pentoxide acts as a catalyzer.
EXPERIMENT 21 --------------- Vanadium pentoxide catalyzes the oxidation of hydroquinone to quinone by hydrogen peroxide.
EXPERIMENT 22 --------------- Vanadium pentoxide does not dissolve in thionyl chloride, but when a small amount of water is added, then it reacts. Vanadium pentoxide dissolves in acetyl chloride, giving a dark red/brown solution.
EXPERIMENT 23 --------------- Vanadium pentoxide does not seem to react with red phosphorus.
End of results for 'vanadium pentoxide'
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