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Experiments for 'sodium thiosulfate'
Below follows a summary of all experiments, matching your
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experiment.
Results for 'sodium thiosulfate':
EXPERIMENT 1 --------------- Thiosulfate gives a purple coordination complex with iron (III). This complex, however, is not stable. With iron (II) no complex is formed. Iron (III) is reduced by thiosulfate after the initial formation of the purple coordination complex. This is shown by adding ferrocyanide, which does not result in formation of an intense dark blue precipitate.
EXPERIMENT 2 --------------- Thiosulfate is capable of reducing ferricyanide, but it is not capable of reducing ferroferricyanide (Prussian blue).
EXPERIMENT 3 --------------- Ferricyanide gives a dark brown coordination complex with ferric ions. This complex is soluble in water. It is easily transformed to the much more stable, dark blue and insoluble ferroferricyanide.
EXPERIMENT 4 --------------- Silver is coordinated by thiosulfate. The silver-thiosulfate complex does not show any of the reactions of free aqueous silver (I).
EXPERIMENT 5 --------------- Silver chloride and silver oxide dissolve in a solution of sodium thiosulfate. The reaction is not very fast.
EXPERIMENT 6 --------------- Silver (I) ions form a precipitate, both with ferrocyanide and with ferricyanide. The precipitate with ferricyanide is decomposed by alkalies, the precipitate with ferrocyanide is more stable. Both compounds are attacked by thiosulfate, which complexes the silver and causes the solid to dissolve again.
EXPERIMENT 7 --------------- A large set of compounds is checked on interaction with concentrated nitric acid. Many reductors react violently with nitric acid.
EXPERIMENT 8 --------------- Rhenium can be oxidized to colorless perrhenate [ReO4]-, with nitric acid. With zinc it can be reduced to a yellow/green species in the presence of hydrochloric acid at sufficient concentration. This species apparently is not reduced any further with borohydride in alkaline environments. In acidic environments, a dark brown/black compound can be formed easily, due to reduction of thiosulfate to sulfide by the borohydride. The sulfide forms a dark compound with rhenium. With sulfite, perrhenate nor the yellow/green compound can be reduced to a lower oxidation state.
EXPERIMENT 9 --------------- Chromium (III) builds a green coordination complex with metabisulfite, not with thiosulfate. When hydrogen peroxide is added, then the complex with metabisulfite is destroyed.
EXPERIMENT 10 --------------- Bismuth forms a yellow complex with thiosulfate. In the presence of thiosulfate, it still forms a deep orange complex with iodide, just as without thiosulfate.
EXPERIMENT 11 --------------- Silver (I) is reduced to metallic silver by metol. This metallic silver is easily oxidized by peroxosulfate. Insoluble silver (I) compounds dissolve in thiosulfate solutions (principle of photography fixer) while metallic silver is not affected. When a mild oxidizer is added, the metallic silver also dissolves (principle of photography reducer, Farmer's reducer).
EXPERIMENT 12 --------------- A clock reaction that precipitates antimony sulfide.
EXPERIMENT 13 --------------- Dichromate ion oxidizes thiosulfate easily in acidic media, but in neutral media it only is oxidizing incompletely, and a solid compound is formed.
EXPERIMENT 14 --------------- The tetrathionate ion is much more stable than the thiosulfate ion in acidic solution.
EXPERIMENT 15 --------------- When thiosulfate ion and nitrite ion are brought together in solution, then nothing happens. When the solution is acidified, then a remarkable reaction occurs. The liquid then quickly turns dark brown and remains clear. Immediately after that, a colorless gas is produced and the color becomes lighter. The color goes from dark brown through brown/orange and yellow to lime green. The liquid remains clear and lime green for a few minutes and then it slowly becomes turbid.
End of results for 'sodium thiosulfate'
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