Experiments for 'sodium borohydride'
Below follows a summary of all experiments, matching your
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experiment.
Results for 'sodium borohydride':
EXPERIMENT 1 --------------- Borohydride is capable of reducing cobalt (II) to the metallic state.
EXPERIMENT 2 --------------- Ferric ions are reduced by borohydride to a black compound. Is this metallic iron or is this iron (II) oxide?
EXPERIMENT 3 --------------- Manganese (II) is not reduced to the metal, it forms a white precipitate with borohydride, which remains white for a long time. This precipitate does not turn brown, as manganese (II) precipitates normally do in alkaline environments.
EXPERIMENT 4 --------------- Borohydride is capable of reducing copper to its metallic state.
EXPERIMENT 5 --------------- Rhenium can be oxidized to colorless perrhenate [ReO4]-, with nitric acid. With zinc it can be reduced to a yellow/green species in the presence of hydrochloric acid at sufficient concentration. This species apparently is not reduced any further with borohydride in alkaline environments. In acidic environments, a dark brown/black compound can be formed easily, due to reduction of thiosulfate to sulfide by the borohydride. The sulfide forms a dark compound with rhenium. With sulfite, perrhenate nor the yellow/green compound can be reduced to a lower oxidation state.
EXPERIMENT 6 --------------- Vanadium in the +4 oxidation state is not reduced to vanadium in a lower oxidation state by borohydride.
EXPERIMENT 7 --------------- Chromium (III) is not reduced to chromium (II) by borohydride. Alkaline chromium (VI) is only reduced slowly by borohydrode. On acidification the reduction goes at once, but no further than the +3 oxidation state.
EXPERIMENT 8 --------------- Gold (III) is reduced by borohydride to its metallic state. A colloidal "solution" of gold is formed.
EXPERIMENT 9 --------------- Borohydride is capable of reducing nickel to the metallic state in aqueous media.
EXPERIMENT 10 --------------- Nickel(II) ion is reduced in slightly alkaline environment by borohydride ion, but only with difficulty, when the mix is heated.
End of results for 'sodium borohydride'
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