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Experiments for 'potassium bromate'
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Results for 'potassium bromate':
EXPERIMENT 1 --------------- Ferrocyanide in acidic environments reacts with bromine in a very peculiar way. An extremely dark compound is formed. This reaction does not occur in neutral environments and this cannot be observed with ferricyanides. What is the dark compound? Is it a coordination complex or a condensation product of many ferric/ferrous ions, close to formation of solid particles?
EXPERIMENT 2 --------------- Bromine reacts with acetylene gas. The bromine disappears and a compound is formed with a peculiar sweetish smell.
EXPERIMENT 3 --------------- Potassium bromate does not react with concentrated formic acid, but when some bromide or hydrochloric acid is added, then the reaction proceeds quickly, carbon dioxide being produced.
EXPERIMENT 4 --------------- Silver (I) gives a precipitate with bromate. The compound silver bromate does not dissolve well in water. When acidified, the compound still does not dissolve, hence the acid HBrO3 is fairly strongly ionized, otherwise the silver bromate would dissolve appreciably. The precipitate of silver bromate, however, still shows strong oxidizing properties, meaning that it is sufficiently soluble for releasing bromate ions in solution, needed for the redox reaction to occur.
EXPERIMENT 5 --------------- Silver (I) forms a precipitate with bromates, while it does not do so with chlorates.
EXPERIMENT 6 --------------- Copper (II) does not form a coordination complex, nor does it form a precipitate with bromate. It does not react.
EXPERIMENT 7 --------------- When bromate, manganese (II), citric acid and sulphuric acid are mixed at certain propertions, then an oscillating reaction occurs, finally resulting in an oily compound, which separates from the aqueous liquid.
EXPERIMENT 8 --------------- When bromate, manganese (II), malonic acid and sulphuric acid are mixed at certain conditions, then a very convincing oscillating reaction occurs, which persists for few minutes, going through a cycle many times, before a final state is reached.
EXPERIMENT 9 --------------- Phosphoric acid is not capable of driving off hydrogen bromide from alkali bromides, nor does it oxidize bromide.
EXPERIMENT 10 --------------- Vanadyl is oxidized by bromate quickly and completely.
EXPERIMENT 11 --------------- Chromium (III) cannot be oxidized to chromium (VI) by vanadium (V) species or bromates in strongly alkaline environments. Peroxodisulfate is capable of achieving this.
EXPERIMENT 12 --------------- When potassium bromate and sulphur are mixed, then a very dangerous mixture is created. This mixture, when ignited, produces an intensely bright flame.
EXPERIMENT 13 --------------- Bromate reacts with concentrated sulphuric acid, releasing bromine and a gas (probably this is oxygen).
EXPERIMENT 14 --------------- Bromate is reduced by sulfite quickly in acidic environments. When an excess amount of bromate is used, then bromine is formed. When an excess amount of sulfite is used, then the bromine is reduced further to bromide.
EXPERIMENT 15 --------------- Potassium bromate reacts vigorously with concentrated hydrochloric acid. A green gas is evolved, but this gas has a color, which is fairly intense. The green gas consists of chlorine, but it also contains bromine, probably combined with chlorine in a compound as BrCl, which is slightly darker green than Cl2.
EXPERIMENT 16 --------------- Potassium bromate is capable of oxidizing hydrogen peroxide, itself being reduced to bromine.
EXPERIMENT 17 --------------- Although the redox potential from bromate to bromine is higher than the potential from perchlorate to chlorate, when chlorate and bromate are mixed, then no reaction occurs. When some hydrochloric acid is added, then a reaction occurs with the chloride ions.
EXPERIMENT 18 --------------- Chlorate and bromate react with hydrochloric acid, but bromate reacts more vigorously. There also is a marked difference between potassium and sodium chlorate. The sodium salt reacts more vigorous with hydrochloric acid, but not as vigorous as potassium bromate. Reactions of bromate are faster than reactions of chlorate, but for sodium and potassium chlorate, the difference can be explained by the speed at which the salt dissolves.
EXPERIMENT 19 --------------- A large amount of sulphur can be added to bromine, before a solid remains in the liquid bromine. The sulphur dissolves in the bromine very easily.
EXPERIMENT 20 --------------- Bromates are more reactive than chlorates in dilute aqueous solutions.
EXPERIMENT 21 --------------- Bromate reacts with chlorides, releasing chlorine. Probably some bromine is produced as well or a bromine/chlorine compound is produced.
EXPERIMENT 22 --------------- Bromate oxidizes iodine to iodate, itself being converted to bromine. Chlorate does not oxidize bromine to bromate, itself being converted to chlorine (at least not quickly).
EXPERIMENT 23 --------------- Potassium bromate reacts with aluminium powder with a very bright light and with crackling noise, but the mix is not like flash powder. Some sulphur is needed for easy ignition of the mix. When a tiny amount of red phosphorus is added to the mix, then it is ignited even more easily, but then it also burns exceptionally fast, almost explosively.
EXPERIMENT 24 --------------- Chromium(III) oxide is extremely inert when it is calcined. It does not dissolve in the common acids, nor in solutions of common bases. The solid, however, can be oxidized by a solution of a bromate.
EXPERIMENT 25 --------------- Formic acid acts as a reductor, while acetic acid does not do so. Formic acid, however, is not that easily reduced. Reduction requires elevated temperature and strong oxidizers.
EXPERIMENT 26 --------------- A mix of finely powdered sodium hypophosphite and potassium bromate forms an energetic mix which can easily be ignited.
EXPERIMENT 27 --------------- Hydroxyl ammonium ion and bromate ion react with each other, but with a delay. Once the reaction starts, it is EXTREMELY violent.
EXPERIMENT 28 --------------- Hydrofluoric acid (48% by weight) dissolves potassium chlorate and potassium bromate much more easily than water. The bromate also slowly decomposes in a peculiar way, which is not observed in other acidic solutions (like sulphuric or nitric acids).
EXPERIMENT 29 --------------- An acidified solution of potassium bromate quickly oxidises solid potassium nitrite to potassium nitrate, the bromate being converted to bromine.
End of results for 'potassium bromate'
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