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Experiments for 'hydroxyl amine sulfate'
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Results for 'hydroxyl amine sulfate':
EXPERIMENT 1 --------------- This is a very nice experiment, involving beautifully coloured compounds, but it is a hazardous experiment as well, due to the use of mercury (II) compounds. Mercury (II) builds a complex with excess iodide, [HgI4]2-, which gives a beautiful bright yellow precipitate with Ag+ and a beautiful bright brick- red precipitate with Cu+.
EXPERIMENT 2 --------------- The ferric ammonium citrate complex is destroyed by acid. The green one is destroyed instantaneously, the brown one slowly is decomposed. The resulting ferric ions can be reduced to almost colorless ferrous ions.
EXPERIMENT 3 --------------- Ferrocyanide and ferricyanide react with hydroxyl amine in an unexpected way. The ferri complex first decolorizes, but then a new colored compound is formed. The ferro complex shows this behaviour immediately.
EXPERIMENT 4 --------------- When an acidified solution of ferric chloride is mixed with a solution of hydroxyl amine sulfate, then an almost colorless compound is formed, but this compound does not seem to be an iron (II) compound.
EXPERIMENT 5 --------------- Hydroxyl amine reacts with ferrocyanides, forming a dark compound. Is the ferrocyanide oxidized by the hydroxyl amine? This reaction occurs in neutral environments, with the hydroxyl amine bound in a hydroxyl ammonium salt.
EXPERIMENT 6 --------------- Hydroxylamine is capable of reducing ferricyanide to ferrocyanide. On heating, however, a yellow compound is formed, which apparently is not ferricyanide. With thiocyanate a pale rose-purple solution is formed on standing. Probably oxygen from the air also takes part in the reaction.
EXPERIMENT 7 --------------- Silver is coordinated by thiosulfate. The silver-thiosulfate complex does not show any of the reactions of free aqueous silver (I).
EXPERIMENT 8 --------------- Silver (I) is not reduced by hydroxyl amine in neutral environments. When made alkaline, it is reduced to metallic silver immediately.
EXPERIMENT 9 --------------- Silver (I) gives a white precipitate with thiocyanate, which does not dissolve in excess ammonia. Hydroxyl amine does not affect this precipitate.
EXPERIMENT 10 --------------- Silver (I) does not give a precipitate with hydroxyl amine sulfate (if concentrations are not too high), but ammonia causes formation of a precipitate, which does not dissolve in excess ammonia.
EXPERIMENT 11 --------------- In alkaline environments, copper (II) shows remarkable behavior, when brought in contact with strong oxidizers or reductors.
EXPERIMENT 12 --------------- Hydroxyl amine sulfate (containing protonated hydroxyl amine) is not capable of reducing copper (II). When the liquid becomes basic (releasing free hydroxyl amine), then the copper (II) is reduced to copper (I).
EXPERIMENT 13 --------------- Copper (II) is reduced by hydroxyl amine very quickly in alkaline environments. Yellow copper (I) hydroxide/oxide is formed.
EXPERIMENT 14 --------------- Copper (II) amine complex is reduced to a colorless copper (I) amine complex by hydroxyl amine. The copper (I) complex is oxidized by oxygen from the air very easily.
EXPERIMENT 15 --------------- When copper (II) is present in hydrochloric acid, then it does not react immediately with hydroxyl ammonium, some heating is required to have a reaction, resulting in formation of a dark green/brown compound. When the liquid is made alkaline with excess ammonia, then it quickly becomes colorless, due to reduction of copper (II) to copper (I), which forms a colorless complex with ammonia. A very peculiar reaction occurs on oxidation by oxygen from air. The liquid is covered by a very thin shiny layer, looking like a strongly coloured oil on water. It is not clear what it is, more research is needed.
EXPERIMENT 16 --------------- Copper (II) chloride is reduced by hydroxyl amine, when dissolved in ethanol. First, the solution becomes much darker and apparently, a mixed oxidation state complex of copper (I) and copper (II) is formed. Finally, all copper (II) is reduced to copper (I). This experiment is another example, which shows that copper (I) and copper (II), when in solution at the same time, form a highly colored complex.
EXPERIMENT 17 --------------- Copper (II) forms a coordination compound with ethyl acetate, which has reacted with hydroxyl amine.
EXPERIMENT 18 --------------- Hydroxyl amine is capable of reducing vanadium (V) to vanadium (IV), but further reduction is not possible with hydroxyl amine.
EXPERIMENT 19 --------------- The result of this experiment is remarkable. Hydroxyl amine, being a strong reductor, appears to oxidize vanadium (IV) to vanadium (V) in alkaline environments. Or is there another compound, which strongly resembles the well-known yellow colour of vanadium (V) in acidic environments and the (almost) colourless appearance of vanadium (V) in alkaline environments?
EXPERIMENT 20 --------------- Chromium (III) apparently builds a coordination complex with hydroxyl amine, but this complex does not simply form from chromium (III) salts and hydroxyl amine. If chromium (III) is formed by means of reduction of chromium (VI) in the presence of hydroxyl amine, then the complex is formed. If hydroxyl amine is added to chromium (III) without redox reaction, then another complex is created.
EXPERIMENT 21 --------------- Chromium (III) forms a lavender precipitate, when combined with hydroxyl amine in alkaline environments. This compound does not dissolve in strongly alkaline environments.
EXPERIMENT 22 --------------- Hydroxyl amine gives a brown coordination complex when it reduces hexavalent chromium to trivalent chromium in alkaline environments. This coordination complex is really due to the hydroxyl amine. When other reducing agents are used in the presence of ammonia in alkaline environments, then no similar reaction product can be obtained.
EXPERIMENT 23 --------------- Tetra chloro auric acid (a.k.a. "gold chloride"), a gold (III) compound is easily reduced to metallic gold, which forms a colloidal solution. With strong reductors, the gold particles formed are so large that they form a dark precipitate.
EXPERIMENT 24 --------------- Hydroxyl amine reacts with acetone, releasing (some) heat. After this reaction, the resulting compound is shown to still be a relatively strongly reducing agent in alkaline solution.
EXPERIMENT 25 --------------- Nitrites react with ammonium and with hydroxyl ammonium ions. In both cases a colorless and odourless gas is formed.
EXPERIMENT 26 --------------- Hydroxyl ammonium ion and bromate ion react with each other, but with a delay. Once the reaction starts, it is EXTREMELY violent.
End of results for 'hydroxyl amine sulfate'
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