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Experiments for 'ferric chloride'
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Results for 'ferric chloride':
EXPERIMENT 1 --------------- Iron (III) compounds with hexacyanoferrate (III) can be reduced easily.
EXPERIMENT 2 --------------- Iron (III) gives a precipitate with S2-, but a redox reaction, resulting in the formation of sulphur also appears to occur.
EXPERIMENT 3 --------------- Thiosulfate gives a purple coordination complex with iron (III). This complex, however, is not stable. With iron (II) no complex is formed. Iron (III) is reduced by thiosulfate after the initial formation of the purple coordination complex. This is shown by adding ferrocyanide, which does not result in formation of an intense dark blue precipitate.
EXPERIMENT 4 --------------- Thiosulfate is capable of reducing ferricyanide, but it is not capable of reducing ferroferricyanide (Prussian blue).
EXPERIMENT 5 --------------- Ferricyanide gives a dark brown coordination complex with ferric ions. This complex is soluble in water. It is easily transformed to the much more stable, dark blue and insoluble ferroferricyanide.
EXPERIMENT 6 --------------- The blue precipitate, formed when ferrocyanide and ferric ions act upon each other is not stable in alkaline environments.
EXPERIMENT 7 --------------- Bleach is not capable of oxidizing ferric hydroxide to the hexavalent ferrate (at least not at 60 C within several minutes).
EXPERIMENT 8 --------------- Ferrous ions give a yellow coordination complex with oxalate. The normal color of ferrous ions is pale green. Ferric ions give a green coordination complex with oxalate. The normal color of ferric ions is yellow/brown. The ferric complex is only formed if the environment is not too acidic.
EXPERIMENT 9 --------------- The experiment described below suggests the formation of a coordination complex between iron and ascorbate. The presence of the ascorbate induces a completely different behavior of ferric/ferrous ions in alkaline environments.
EXPERIMENT 10 --------------- Ferric ions apparently form a coordination complex with glucose in alkaline environments. Normally ferric ions give a brown precipitate in strong alkaline liquids, with glucose the liquid remains clear.
EXPERIMENT 11 --------------- Ferric ions form a coordination complex with sulfite.
EXPERIMENT 12 --------------- Phenol and its derivatives form highly colored coordination complexes with ferrous and ferric ions.
EXPERIMENT 13 --------------- Dithionite is not capable of reducing ferric oxide/hydroxide to an iron (II) compound in alkaline environments.
EXPERIMENT 14 --------------- Dithionite reduces ferric ions to ferrous ions quickly in acidic environments.
EXPERIMENT 15 --------------- Dithionite is capable of reducing prussian blue (ferric ferro cyanide).
EXPERIMENT 16 --------------- Ferric chloride reacts with bleach and forms a brown precipitate. No higher oxidation products of iron can be observed.
EXPERIMENT 17 --------------- Although p-aminophenol and metol are similar compounds (metol is the sulfate salt of p-aminophenol with a H-atom at the amino-group replaced by a methyl group) they show fairly large differences as far as complex- formation is concerned with ferric compounds. Metol reacts more slowly and the color of the compounds differ.
EXPERIMENT 18 --------------- When an acidified solution of ferric chloride is mixed with a solution of hydroxyl amine sulfate, then an almost colorless compound is formed, but this compound does not seem to be an iron (II) compound.
EXPERIMENT 19 --------------- Iron (III) builds a coordination complex with phosphates.
EXPERIMENT 20 --------------- Ferric ions are reduced by borohydride to a black compound. Is this metallic iron or is this iron (II) oxide?
EXPERIMENT 21 --------------- Permanganate is capable of oxidizing thiocyanate in acidic environments: The result is a pink solution, more intensely colored than manganese (II) ions (which are almost colorless).
EXPERIMENT 22 --------------- Sulfide gives precipitates with some metals, which do not dissolve in strong acids. These sulfides, however, can easily be dissolved, when an oxidizing agent is used. Sulfide is easily oxidized by moderately strong oxidizers.
EXPERIMENT 23 --------------- This sequence of experiments shows that sulfite is capable of reducing silver (I), copper (II) and iron (III), but that these reactions all show their own peculiarities. Sulphur in the +4 oxidation state is a mild reductant.
EXPERIMENT 24 --------------- Copper (II) reacts with thiocyanate in a complex way.
EXPERIMENT 25 --------------- Copper gives a coordination complex with catechol, but only in alkaline environments. This complex is easily oxidized by oxygen from air. Iron also forms a complex in acidic media, probably by a combined red/coordination reaction.
EXPERIMENT 26 --------------- Nitrous acid (or its decomposition product) forms a dark brown coordination complex with ferric ions. With copper (II) also a coordination complex is formed. In relatively strongly acidic environments, these coordination complexes are destroyed/not formed.
EXPERIMENT 27 --------------- Tannine (a polyphenolic compound of large molecular weight of indeterminate composition) reacts with many metal ions, forming highly coloured complexes. It also shows some other reactions. The exact type of reactions is not always clear. The tannine, used in these experiments, was brown. It's intended use is as an additive for making wine.
EXPERIMENT 28 --------------- Nickel (II) forms a complex with citrate. In a strongly alkaline environment the nickel (II) does not precipitate. With just a small amount of ferric ions present in the liquid, the complete liquid solidifies to a gelatin- like constitution. When the same experiment is done, without the nickel (II) present, no solidification is observed.
EXPERIMENT 29 --------------- Hydroquinone is oxidized by ferric chloride to quinone. An intermediate dark green compound is formed before all hydroquinone is oxidized.
EXPERIMENT 30 --------------- Ferric chloride enhances the oxidation of hydroquinone by hydrogen peroxide considerably. Besides this, a coordination complex appears to be formed when ferric chloride is added to an hydroquinone/peroxide solution.
EXPERIMENT 31 --------------- Hydroquinone can be oxidized by ferric chloride. If not too much ferric chloride is added, then a coordination complex of the oxidation product with hydroquinone is formed and crystals of this compound separate from the liquid.
EXPERIMENT 32 --------------- Pyrogallol gives rise to many colored products on oxidation and coordination. More investigation is needed in order to get more insight in all these colors and the conditions under which they are formed.
EXPERIMENT 33 --------------- The coordination complexes formed by iron-salts and phenol-like photographic developers show very typical reactions with hydrogen peroxide. Many times these reactions result in oxidation products which are not dark colored, as opposed for oxidation by atmospheric oxygen.
EXPERIMENT 34 --------------- Copper(II) ion and iron(III) ion form complexes with acetyl acetate (acac) in aqueous solution. Cobalt does not form a complex, at least not visibly.
EXPERIMENT 35 --------------- Ferric chloride dissolves in acetic anhydride very well, forming a beautifully colored deep red/brown solution. The color of this solution is very bright.
End of results for 'ferric chloride'
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