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Experiments for 'cobalt sulfate'
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Results for 'cobalt sulfate':
EXPERIMENT 1 --------------- Cobalt (II) gives a precipitate with bicarbonate, which probably is cobalt carbonate. This precipitate is formed, while driving off CO2.
EXPERIMENT 2 --------------- Cobalt (II) gives a blue precipitate with hydroxide, but this precipitate quickly turns pink / purple / light brown after its formation.
EXPERIMENT 3 --------------- Cobalt (II) gives a deep blue precipitate with silicates.
EXPERIMENT 4 --------------- Cobalt (II) gives a precipitate with bicarbonate, which reacts with hydrogen peroxide, probably forming a cobalt (III) compound.
EXPERIMENT 5 --------------- Cobalt (II) salts give a blue/green precipitate when dilute ammonia is added. This precpitate is fairly stable towards air. When more concentrated ammonia is used, then a dark brown compound is formed, but this compound is formed by contact with air. On addition of hydrogen peroxide also a very dark brown compound is formed. When the pH is increased strongly, then the blue precipitate is not stable anymore, instead a dark bright blue compound is formed, which, however, quickly turns pink. When a large amount of ammonia is replaced by ammonium, then the blue precipitate is not formed anymore, but a coordination complex is formed, which is very easily oxidized by oxygen from the air.
EXPERIMENT 6 --------------- Cobalt sulfide does not dissolve in dilute acids and it does not dissolve in concentrated hydrochloric acid (at least not easily). With the help of hydrogen peroxide it is possible, however, to dissolve the compound.
EXPERIMENT 7 --------------- Cobalt (II) gives a green precipitate with ferrocyanide and a dark red/ purple precipitate with ferricyanide. The green precipitate cannot be converted to the red one by means of oxidation by hydrogen peroxide, but another, dark blue, compound is formed.
EXPERIMENT 8 --------------- Cobalt sulfate dissolves in methanol, albeit not as well as in water. The liquid obtained is colored quite intensely. The dilute solution of cobalt sulfate in methanol looks more pink/purple than even the most concentrated aqueous solution. With thiocyanate a deep blue complex is formed in methanol.
EXPERIMENT 9 --------------- Borohydride is capable of reducing cobalt (II) to the metallic state.
EXPERIMENT 10 --------------- In this experiment, some of Werner's experiments are repeated. Here it is shown that cobalt forms beautifully colored carbonato complexes. The exact complex formed, depends on the experimental conditions. It is remarkable what kinds of reactions are shown by cobalt in its complexes and it is really difficult to precisely determine what is happening and it even is difficult already to get the same results without precisely specifying the exact experimental conditions (e.g. using HCl instead of H2SO4 already results in a different outcome).
EXPERIMENT 11 --------------- Aluminum reacts vigorously with water, when its passivating layer of oxide is effectively destroyed. This can be achieved by using tetrachloro or tetrabromo complexes of copper (II). Acid can also be used to destroy the passivating layer, but this takes considerably more time. Cobalt has a similar effect as copper (II), but it is less pronounced.
EXPERIMENT 12 --------------- Copper(II) ion and iron(III) ion form complexes with acetyl acetate (acac) in aqueous solution. Cobalt does not form a complex, at least not visibly.
EXPERIMENT 13 --------------- A solution of cobaltous acetate is hydrolysed when the solution is heated. When the liquid cools down again, then the effect is reversed again. The visual result is formation of a precipitate on heating and the slow redissolving of the precipitate on cooling down.
EXPERIMENT 14 --------------- When hydrated sulfate-salts are heated, which only loose water, then their properties strongly change. The color changes, but also the solubility properties change a lot. The sulfate salts loose water easily, but no acid (H2SO4 or SO3).
EXPERIMENT 15 --------------- Cyanate ion forms complexes with many metal ions. These complexes have a strong color and are not stable in acidic solution.
End of results for 'cobalt sulfate'
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