Experiments for 'ammonium persulfate'
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experiment.
Results for 'ammonium persulfate':
EXPERIMENT 1 --------------- Persulfate is not capable of oxidizing manganese to the (VII) state in acidic environments.
EXPERIMENT 2 --------------- Permanganate is capable of oxidizing thiocyanate in acidic environments: The result is a pink solution, more intensely colored than manganese (II) ions (which are almost colorless).
EXPERIMENT 3 --------------- Persulfate decomposes in strongly alkaline environments.
EXPERIMENT 4 --------------- Chromium (III) can be oxidized to chromium (VI) by persulfate in alkaline environments.
EXPERIMENT 5 --------------- A precipitate of nickel hydroxide is oxidized by persulfate to a black compound (probably NiO2).
EXPERIMENT 6 --------------- Nickel (II) gives a black precipitate when treated with hydroxide and persulfate at the same time. It is expected that this is an higher oxide of nickel (NiO2).
EXPERIMENT 7 --------------- Nickel does not appear to build coordination complexes with thiocyanate, not even if acetone is added (in contrast to cobalt). Ni(OH)2 is oxidized to a dark compound by persulfate, even in the presence of a reducing agent like acetone.
EXPERIMENT 8 --------------- Silver (I) is reduced to metallic silver by metol. This metallic silver is easily oxidized by peroxosulfate. Insoluble silver (I) compounds dissolve in thiosulfate solutions (principle of photography fixer) while metallic silver is not affected. When a mild oxidizer is added, the metallic silver also dissolves (principle of photography reducer, Farmer's reducer).
EXPERIMENT 9 --------------- Titanium slowly dissolves in concentrated hydrochloric acid, forming deep blue/violet titanium (III) ions. On addition of hydrogen peroxide these are oxidized to titanium (IV), which in turn forms a deep red coordination complex with hydrogen peroxide. The deep red coordination complex is only stable in acidic to neutral media. It also is easily reduced by nitrite. It is not affected strongly by persulfate. With fluoride, a light yellow compound is formed, but the formation of that may also be due to rise of pH.
End of results for 'ammonium persulfate'
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