Tellurium
Tellurium is a crystalline solid, with a remarkable
silvery metallic lustre. Although the element looks like a metal, it certainly
is not a metal. It only vaguely has metallic properties.
The element has some metallic properties, but only very
weakly. When tellurium is brought in contact with dilute hydrochloric acid in
intimate contact with air, then it dissolves, forming a small amount of
tellurium (IV) ions. These, however readily hydrolyse to hydrous tellurium
dioxide.
Tellurium is quite resistant to oxidation, but aqueous
solutions of tellurium compounds can be obtained by adding finely ground
tellurium to a solution of chloric acid (e.g. sodium chlorate dissolved in
dilute sulphuric acid or dilute nitric acid). Another oxidizer, capable of
dissolving tellurium is potassium permanganate, dissolved in dilute nitric acid.
The compound formed is orthotelluric acid, H6TeO6.
Elementary tellurium is available on eBay from various
sellers, who sell the element in the form of chunks, ranging from a few 100 mg
to over 100 grams. The element is quite expensive, its price is slightly less
than $1 per gram, when purchased in 50+ gram quantities. Tellurium is not a
compound to start with in a home lab. Handling tellurium compounds certainly is
not without risk (see below) and the tellurium-chemistry, which can be studied
by the home chemist with basic equipment only, is very limited.
In its compounds, tellurium can have oxidation states -2,
+4 and +6. The -2 oxidation state is in the form of tellurides. Tellurides can
be prepared by direct reaction between a finely powdered metal and finely
powdered tellurium. The higher oxidation states are available by dissolving
tellurium in a strongly oxidizing acid mixture (see above). No compounds of
tellurium are available to the general public.
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