Lanthanoids (lanthanides)
The lanthanoids are all metals, which are quite reactive.
They all are attacked by water, forming the hydroxide and hydrogen gas. Some of
the lanthanoids must be kept under mineral oil, otherwise they are oxidized to
the oxide or the hydroxide quickly. Below, pictures of erbium (left) and
praseodymium (right) are given. The other lanthanides look quite similar.
The chemistry of these metals also is very similar for all of
them. Their most important oxidation state is +3. In water they form aqueous Ln3+
ions (here Ln stands for one of the lanthanoid elements). Only the metals cerium
and europium have aqueous redox chemistry, allowing Ce4+ and Eu2+.
Cerium (IV) is a fairly strong oxidizer and europium (II) is a strong reductor.
The aqueous lanthanoid ions mostly are colorless, but
there are a few exceptions. Cerium (IV) is deep yellow, praseodymium (III) is
light green and erbium (III) is light pink. Some other ions are very pale yellow, most
notable samarium (III). All these metals are purely basic and form insoluble
hydroxides.
For the home chemist, the lanthanoids are of limited
interest. They all are strong reductors, but when magnesium, aluminium and zinc
are available, then the lanthanoid metals do not add very much to a home lab.
Most lanthanoid metals are offered on eBay on a regular
basis. Prices are varying widely, due to differences in abundance of the
elements. None of these elements, however, is particularly cheap, some of them
are very expensive, exceeding the price of silver by a large factor.
Compounds of these elements are hard to find for the
general public. Sometimes one of the oxides of the metals is offered on eBay.
These oxides, however, may be of limited interest for the home chemist, due to
inertness, caused by calcining of the oxide. A compound, which may be available
from chemical supply houses is cerium (IV) sulfate or cerium (IV) ammonium
sulfate or nitrate.
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